Bicyclo[4.2.0]oct-(8)-ene-8-carboxylic acid AROMP Polymer

Facile preparation of bicyclo[4.2.0]oct-(8)-ene-8-carboxylic acid to prepare the key amide monomer for polymerization.

Bicyclo[4.2.0]oct-1(8)-ene-8-carboxamides undergo alternating ring-opening metathesis polymerization (AROMP) with cyclohexene.

From the laboratory of Nicole S. Sampson, PhD, Stony Brook University.

Catalog Number Product DataSheet Size AVAILABILITY Price Qty
Bicyclo[4.2.0]oct-(8)-ene-8-carboxylic acid AROMP Polymer
100mg In stock
Regular Price:$120.00
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Product Type: Small Molecule
Name: Bicyclo[4.2.0]oct-8-ene-8-carboxylic acid
Chemical Formula: C9H12O2
Molecular Weight: 152.19
Format: White solid
Purity: >95%, NMR
Solubility: CH2Cl2, THF, DMF
Spectral Information: 1H NMR, 13C NMR
Comments: Hygroscopic
Storage: -20C
Shipped: Room temperature

From the laboratory of Nicole S. Sampson, PhD, Stony Brook University.
  1. Chen L, Li L, Sampson NS. Access to Bicyclo[4.2.0]octene Monomers To Explore the Scope of Alternating Ring-Opening Metathesis Polymerization. J Org Chem. 2018 Mar 2;83(5):2892-2897.
  2. Tan, L., Li, G., Parker, K., and Sampson, N. S. (2015) “Ru-catalyzed Isomerization Provides Access to Alternating Copolymers via Ring-Opening Metathesis Polymerization,” Macromolecules, 48, 4793-4800. DOI: 10.1021/acs.macromol.5b01058 PMC4520717.
  3. Flelming I, and Harley-Mason J. The Reaction of Enamines with Electrophilic Olefins. A Synthesis of Cyclobutanes. J. Chem. Soc., 1964, 2165-2174.

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