Bicyclo[4.2.0]oct-(8)-ene-8-carbonitrile AROMP Polymer

Facile preparation of bicyclo[4.2.0]oct-(8)-ene-8-carbonitrile that can be used to prepare the aldehyde monomer amongst others for polymerization.

Bicyclo[4.2.0]oct-1(8)-ene-8-carboxldehydes and nitriles undergo alternating ring-opening metathesis polymerization (AROMP) with cyclohexene.

From the laboratory of Nicole S. Sampson, PhD, Stony Brook University.

Catalog Number Product Size AVAILABILITY Price Qty
ESB012
Bicyclo[4.2.0]oct-(8)-ene-8-carbonitrile, 100mg
100mg In stock
Price: $100.00

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Specifications
Product Type: Small Molecule
Name: Bicyclo[4.2.0]oct-1(8)-ene-8-carbonitrile
Chemical Formula: C9H11N
Molecular Weight: 133.19
Format: Yellow oil
Purity: >95%, NMR
Solubility: CH2Cl2, hexanes, THF, DMF
Spectral Information: 1H NMR, 13 C NMR, HSQC, IR
Storage: -80C
Shipped: Dry ice
Provider
From the laboratory of Nicole S. Sampson, PhD, Stony Brook University.
References
  1. Chen L, Li L, Sampson NS. Access to Bicyclo[4.2.0]octene Monomers To Explore the Scope of Alternating Ring-Opening Metathesis Polymerization. J Org Chem. 2018 Mar 2;83(5):2892-2897.
  2. Flelming I, and Harley-Mason J. The Reaction of Enamines with Electrophilic Olefins. A Synthesis of Cyclobutanes. J. Chem. Soc., 1964, 2165-2174.

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