Bicyclo[4.2.0]oct-(8)-ene-8-carboxylic acid AROMP Polymer
![Bicyclo[4.2.0]oct-(8)-ene-8-carboxylic acid](https://www.kerafast.com/MediaStorage/Product/Images/Large/1664_2001202001265616630.jpg "Bicyclo[4.2.0]oct-(8)-ene-8-carboxylic acid AROMP Polymer")
Facile preparation of bicyclo[4.2.0]oct-(8)-ene-8-carboxylic acid to prepare the key amide monomer for polymerization.
Bicyclo[4.2.0]oct-1(8)-ene-8-carboxamides undergo alternating ring-opening metathesis polymerization (AROMP) with cyclohexene.
From the laboratory of Nicole S. Sampson, PhD, Stony Brook University.
Facile preparation of bicyclo[4.2.0]oct-(8)-ene-8-carboxylic acid to prepare the key amide monomer for polymerization.
Bicyclo[4.2.0]oct-1(8)-ene-8-carboxamides undergo alternating ring-opening metathesis polymerization (AROMP) with cyclohexene.
From the laboratory of Nicole S. Sampson, PhD, Stony Brook University.
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Specifications
| Product Type: | Small Molecule |
| Name: | Bicyclo[4.2.0]oct-8-ene-8-carboxylic acid |
| Chemical Formula: | C9H12O2 |
| Molecular Weight: | 152.19 |
| Format: | White solid |
| Purity: | >95%, NMR |
| Solubility: | CH2Cl2, THF, DMF |
| Spectral Information: | 1H NMR, 13C NMR |
| Comments: | Hygroscopic |
| Storage: | -20C |
| Shipped: | Room temperature |
Provider
From the laboratory of Nicole S. Sampson, PhD, Stony Brook University.
References
- Chen L, Li L, Sampson NS. Access to Bicyclo[4.2.0]octene Monomers To Explore the Scope of Alternating Ring-Opening Metathesis Polymerization. J Org Chem. 2018 Mar 2;83(5):2892-2897.
- Tan, L., Li, G., Parker, K., and Sampson, N. S. (2015) “Ru-catalyzed Isomerization Provides Access to Alternating Copolymers via Ring-Opening Metathesis Polymerization,” Macromolecules, 48, 4793-4800. DOI: 10.1021/acs.macromol.5b01058 PMC4520717.
- Flelming I, and Harley-Mason J. The Reaction of Enamines with Electrophilic Olefins. A Synthesis of Cyclobutanes. J. Chem. Soc., 1964, 2165-2174.
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