Bicyclo[4.2.0]oct-(8)-ene-8-carbonitrile AROMP Polymer
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Facile preparation of bicyclo[4.2.0]oct-(8)-ene-8-carbonitrile that can be used to prepare the aldehyde monomer amongst others for polymerization.
Bicyclo[4.2.0]oct-1(8)-ene-8-carboxldehydes and nitriles undergo alternating ring-opening metathesis polymerization (AROMP) with cyclohexene.
From the laboratory of Nicole S. Sampson, PhD, Stony Brook University.
Facile preparation of bicyclo[4.2.0]oct-(8)-ene-8-carbonitrile that can be used to prepare the aldehyde monomer amongst others for polymerization.
Bicyclo[4.2.0]oct-1(8)-ene-8-carboxldehydes and nitriles undergo alternating ring-opening metathesis polymerization (AROMP) with cyclohexene.
From the laboratory of Nicole S. Sampson, PhD, Stony Brook University.
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Specifications
| Product Type: | Small Molecule |
| Name: | Bicyclo[4.2.0]oct-1(8)-ene-8-carbonitrile |
| Chemical Formula: | C9H11N |
| Molecular Weight: | 133.19 |
| Format: | Yellow oil |
| Purity: | >95%, NMR |
| Solubility: | CH2Cl2, hexanes, THF, DMF |
| Spectral Information: | 1H NMR, 13 C NMR, HSQC, IR |
| Storage: | -80C |
| Shipped: | Dry ice |
Provider
From the laboratory of Nicole S. Sampson, PhD, Stony Brook University.
References
- Chen L, Li L, Sampson NS. Access to Bicyclo[4.2.0]octene Monomers To Explore the Scope of Alternating Ring-Opening Metathesis Polymerization. J Org Chem. 2018 Mar 2;83(5):2892-2897.
- Flelming I, and Harley-Mason J. The Reaction of Enamines with Electrophilic Olefins. A Synthesis of Cyclobutanes. J. Chem. Soc., 1964, 2165-2174.
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